Document Type
Article
Publication Date
1998
Abstract
The group III metal dimers Ga2 and In2 and the newly identified intermetallic molecule GaIn were investigated in a Knudsen cell-mass spectrometric study of the vapors over gallium–indium alloys. From the all-gas equilibria analyzed by the second-law and third-law methods the following dissociation energies were derived; D00 (Ga2)=110.8±4.9 kJ mol−1, D00 (In2)=74.4±5.7 kJ mol−1, D00 (GaIn)=90.7±3.7 kJ mol−1. The value here measured for the dissociation energy of In2 is discussed and compared with a previous experimental determination and with the results of more recent theoretical investigations.
DOI
10.1063/1.477041
Recommended Citation
Balducci, G., & Gigli, G. (1998). Dissociation energies of the Ga[sub 2], In[sub 2], and Galn molecules. Journal Of Chemical Physics, 109(11), 4384.
Comments
Copyright 1998 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.
The following article appeared in Balducci, G., & Gigli, G. (1998). Dissociation energies of the Ga[sub 2], In[sub 2], and Galn molecules. Journal Of Chemical Physics, 109(11), 4384. and may be found at http://dx.doi.org/10.1063/1.477041.