Document Type
Article
Publication Date
2000
Abstract
High-temperature Knudsen cell mass spectrometry has been used to study the equilibria involving the B2Nmolecule over the Si–BN system. Thermal functions needed in the evaluation of the mass spectrometric equilibrium data have been calculated from available experimental and theoretical molecular parameters. The enthalpy changes for the reactions2B(g)+Si2N(g)=B2N(g)+2Si(g),and BN(s)+B(g)=B2N(g)have been measured. The following atomization enthalpy,ΔaHo0,and enthalpy of formation,ΔfHo298.15,in kJ mol−1, of1045.5±18 and551.3±18 for theB2N molecule have been determined from these reactionenthalpies. Atomization energies of similar molecules have been compared and discussed.
DOI
10.1063/1.1319353
Recommended Citation
Meloni, G., Baba, M. S., & Gingerich, K. A. (2000). Knudsen cell mass spectrometric investigation of the B[sub 2]N molecule. Journal Of Chemical Physics, 113(20)
Comments
Copyright 2000 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.
The following article appeared in Meloni, G., Baba, M. S., & Gingerich, K. A. (2000). Knudsen cell mass spectrometric investigation of the B[sub 2]N molecule. Journal Of Chemical Physics, 113(20) and may be found at http://dx.doi.org/10.1063/1.1319353.